V.K. Dubrovich
1 Special Astrophysical Observatory, Nizhnij Arkhyz, K.-Ch.R.,
357147, Russia (dubr@sao.ru)
AbstractThe luminescence process for proto-objects moving with a peculiar velocity at high redshift is considered. It is shown that some primordial molecules could produce low-frequency photons (which correspond to the rotational lines) by decaying high-frequency rovibration photons from the CMBR. Due to the rather different numbers of these photons, a huge enhancement (relative to the pure reflection mechanism) of the emission line intensity from the proto-objects could occur at the appropriate wavelengths.
Key words: Radiation
cosmology: theory
molecular processes
So, now we can try to investigate the next level of observational effects
which are provided by proto-objects in the post recombination epoch. One
of the most probable classes of such effects will be considered here. They
are the so-called SSF - Spectral Spatial Fluctuations (Dubrovich,
1994). Actually, they are the proto-objects at high redshift
- 10 z
300, which must contain some amount of molecules and which have a peculiar
velocity
relative
to the CMBR. There are necessary and sufficient conditions for the SSF
to be produced. The theory of this process was discussed by Dubrovich
(1977, 1983,
1994)
and by Maoli
et al. (1994). Some experiments were described by De
Bernardis (1992) and some plans by Signore
et al.(1993).
All this work is based on the simplest mechanism of the SSF formation
- pure reflection of the CMBR photons due to the opacity of a proto-object
in narrow spectral lines and the Doppler shift in frequency due to its
peculiar velocity. In this paper another mechanism will be considered.
Let us consider this process in detail. Taking into account only those
chemical elements (the most abundant) which are predicted by the pure Big
Bang model - H, He, D, 3 He, Li, and their ions, we can list
the most probable molecules in the primordial matter at z = 100-200: H2,
H , HD, HD
,
HeH
, LiH, LiH
,
H2 D
,
3
He4 He
.
All other molecules should be considered more critically, because their
appearance is caused by some non-standard circumstances: non-equilibrium
nuclear synthesis at the early times (z=
),
or star formation at z = 200-300, etc. But, as was mentioned before, the
pure model of the Universe is the most probable one. So, we won`t consider
any other molecules here.
For obtaining the greatest interaction between molecules and photons,
two values are important - the cross-section for scattering and the concentration
(or relative abundance) of this molecule. The first parameter depends on
the specific quantum structure of the molecule - its symmetry and charge.
The second one depends on the abundance of the chemical elements of which
it is composed and on the rate of the appropriate chemical reactions. According
to these constraints, we should take into consideration only those molecules
which have a large enough dipole moment and relatively high abundance.
These are: HD ,
HeH
, LiH, H2
D
, 3
He4 He
.
The molecules H2 and H
have no dipole moment, while HD has a rather small dipole moment and the
abundance of D is not high enough. LiH
has a very low potential of dissociation and so its abundance in a hot
Universe is very small. So, we can expect only a small number of molecules
to be visible from the early Universe: HD
,
HeH
, LiH, H2
D
, 3
He4 He
.
here is
the component of the peculiar velocity along the line of sight and c
is the speed of light. It should be pointed out, that if this fluctuation
is caused by the interaction with a resonant system, it must occur only
at the corresponding wavelength and, what is very important, there should
be no influences from the one resonance to any other. In our case it means
that this effect could be at the wavelength corresponding to the rotational
and the rovibration transitions, but the amplitudes of the
from the separate transitions are fully independent. It is one of the fundamental
properties of pure reflection.
On the contrary, the luminescence process causes the appearance of some photons at one wavelength due to the absorption of the appropriate photons at another wavelength. This new property of the process of interaction of matter and radiation leads us to new possibilities for SSF formation.
According to the previous investigations by Dubrovich (1977) and Maoli et al. (1994), and our new considerations, we obtain:
where is
the redshift of molecule's recombination by Saha,
is derived from this equation at
,
and
.. The
value of the optical depth (for rotovibrational transitions here) we will
estimate on the base of the expressions obtained by Dubrovich
(1994) for pure rotational transitions. The accuracy of
such an estimation maybe not more than one order of magnitude.
where ,
are the total and the baryonic average densities of the matter relative
to the critical one,
is the abundance of the molecule relative to the atomic hydrogen, z is
the redshift of the proto-object, H is the Hubble constant, normalized
to
= 75km/s/Mpc,
is the specific molecule constant, d is the dipole moment of the
molecule,
and
are temperature
of CMBR and the critical density at z = 0.
In Table 1 we present the main information about the most probable and highly interacting primordial molecules and some estimate of the fundamental parameters that could be measured.
here:
is the dissociation potential of the molecule,
is the wavelength of the first rotational transition (
=c/2
),
is the wavelength of the rovibration transition (
),
refers to the highest wavelength where this molecule could now be seen,
is the limit to the molecule abundance which could be reached if we assume
that
/c
=
and that
the observational limit which can be achieved is
,
is the lower limit which could be placed on the peculiar velocity if we
assume
1
and an observational limit of the
.
The triatomic molecule H2 D
is more complicated than the other molecules in Table
1
Now, we can write the expression for
in a more simple form:
In order to search for these molecules, the most auspicious wavelength
regions (for the first rotational lines) can be found in Fig.2.
The expected values of
are shown as a function of wavelength for each molecule and correspond
to the value of
.
The red wings of these curves are actually due to the rate of recombination
of each molecule, assuming Saha recombination rates. The blue wings are
described by expression (8). The second rotational line of each molecule
has a factor of two higher frequency and a value of K which is four times
lower than the first one.
Fig. 2. The value of for several molecules
Table 1.
Here are some comments to Table 1.
LiH: This is a very important molecule, because it consists of primordial
Li. Its abundance is a good test for the epoch of nuclear synthesis in
the early Universe. Its large dipole moment and relatively low frequency
of the rotational and rovibration transitions lead to the high value of
K. But unfortunately, its small abundance and some difficulties with the
chemical processes of forming this molecule lead to a non-optimistic prediction
for . Even
so, this value of
,
eqn. 16 and the peak value of
from Fig.
2 lead to predicted values as high as about
=
for
= 0.1.
HD : This
is also an important molecule, due to the presence of primordial deuterium,
D. The abundance of D is about 5 orders of magnitude larger, than that
of Li. But HD
has a dipole moment about 10 times less than LiH and a cross-section which
is 100 times smaller. Another small factor is the abundance of H
at redshift z = 200, which might be about
relative to that of neutral hydrogen. Due to the relatively high frequency
of the rotational and rovibration transitions, the resulting value of K
is not very large. But, if high sensitivity were reached, this molecule
might be seen.
HeH : This
molecule does not have any low abundance constituents. There are only two
small factors which lead to a low abundance: a high rate coefficient for
destruction (by electron recombination and collisions with the neutral
atoms of hydrogen) compared with the rate coefficient of formation, and
a small abundance of H
at high redshift. But it might be the most likely molecule to be searched
for.
H2 D :
This is the simplest triatomic molecule with a high dipole moment. It contains
primordial deuterium. Due to the presence in its spectrum of very low frequency
transitions, the value of K can be very high. In Table 1 the value K0
corresponds to
.
It is very important that the redshift of the recombination H2
D
be relatively
high.
The expected abundances of these molecules in the early Universe are discussed by many authors (Lepp and Shull,1984, Puy et al, 1993, Palla et al, 1995, Maoli et al, 1996, Stancil et al, 1996a) and more recent results by Stancil et al.(1996b).
In order to observe SSF due to all these molecules, let us give some
simple estimates of their main parameters. These are diffuse, extended
objects, which will have only the narrow emission lines with the low brightness
temperature in these lines. The width
of these lines depends on the object's size (linear - L or angular -
)
(Dubrovich,
1982):
Here M is the mass of the proto-object,
is the mass of the Sun. At the redshift z = 100, if
then a protogalaxy with the mass
has
A proto-object with the mass of an ordinary cluster of galaxies, ,
will have an angular size:
The value of the peculiar velocity at the redshift z might be:
These parameters would be the most probable for the standard model of
the Universe.
where
is a noise temperature . The IRAM observation (de Bernardis at al.,1993)
has the
=1000 K. At
=13cm one can has
=100 K. Taking into account 100 times' less
here one could see that absolute value of
measured in both cases are equal. But the
which is predicted at
=13 cm is about three order of magnitude more than at
= 1.3 mm. There is another problem for observations at low frequency -
it is that we need to have a full aperture radiotelescope with an appropriate
angular resolution. For proto-objects with
size it must be about 600 m diameter. For this case
MHz and
from (24) is